J. Chem. Nat. Mater. Avsar, A., Vera-Marun, I.J., Tan, J.Y., Watanabe, K., Taniguchi, T., Castro Neto, A.H., Ozyilmaz, B.: Air-stable transport in graphene-contacted, fully encapsulated ultrathin black phosphorus-based field-effect transistors. one of the most common allotropes of phosphorus and is considered to be a derivative of the P4 molecule Adv. Black phosphorus, unlike graphene, is a semiconductor with a sizeable gap (Asahina and Morita, 1984; Keyes, 1953; Morita, 1986). PERSPECTIVE The renaissance of black phosphorus Xi Linga, Han Wangb,1, Shengxi Huanga, Fengnian Xiac, and Mildred S. Dresselhausa,d,1 aDepartment of Electrical Engineering and Computer Science anddDepartment of Physics, Massachusetts Institute of Technology, Cambridge, MA 02139; bMing Hsieh Department of … : Tuning of the electronic and optical properties of single-layer black phosphorus by strain. Abstract. sites of that element in the structure. Am. Nat. : Light-emitting diodes by band-structure engineering in van der Waals heterostructures. Fig. Nat. Rev. It can be sublimed in the air and has either rhombohedral crystals or opaque monoclinic. Phosphorus pentoxide was used in the early and mid-20thcentury to procure phosphoric acid, by dissolving the former in water. Part of Springer Nature. : Electrical and thermoelectric transport by variable range hopping in thin black phosphorus devices. Jain, A., McGaughey, A.J.H. Sci. : Phosphorene: an unexplored 2D semiconductor with a high hole mobility. Maruyama, Y., Suzuki, S., Kobayashi, K., Tanuma, S.: Synthesis and some properties of black phosphorus single crystals. Here, we report the synthesis of the black phosphorus–structured nitrogen at 146 GPa and 2200 K. Metastable black phosphorus–structured nitrogen was retained after quenching it to room temperature under compression and characterized in situ during decompression … Engl. Chem. Fei, R., Faghaninia, A., Soklaski, R., Yan, J.A., Lo, C., Yang, L.: Enhanced thermoelectric efficiency via orthogonal electrical and thermal conductances in phosphorene. Peng, J., Lai, Y.Q., Chen, Y.Y., Xu, J., Sun, L.P., Weng, J.: Sensitive detection of carcinoembryonic antigen using stability-limited few-layer black phosphorus as an electron donor and a reservoir. J. Photon. Liu, H., Du, Y.C., Deng, Y.X., Ye, P.D. 2D Mater. Note the primitive cell may appear less symmetric than the conventional cell representation (see "Structure Type" selector below the 3d structure). Int. compared against each other. Because of these structural similarities black phosphorus is also flaky like graphite and possesses other similar properties. Li, D., Castillo, A.E.D.R., Jussila, H., Ye, G., Ren, Z., Bai, J., Chen, H.L., Sun, Z., Bonaccorso, F.: Black phosphorus polycarbonate polymer composite for pulsed fibre lasers. Sci. : Intrinsic and extrinsic performance limits of graphene devices on SiO, Yong, K.S., Otalvaro, D.M., Duchemin, I., Saeys, M., Joachim, C.: Calculation of the conductance of a finite atomic line of sulfur vacancies created on a molybdenum disulfide surface. J. Phys. Electrical and optical experiments [l, 2] on polycrystalline black phosphorus show that it is a narrow gap semiconductor with an energy gap … Download spectra for every symmetrically equivalent Phys. Xie, H., Shao, J., Ma, Y., Wang, J., Huang, H., Yang, N., Wang, H., Ruan, C., Luo, Y., Wang, Q.Q., Chu, P.K., Yu, X.F. Martinez, C.C.M., Sofer, Z., Pumera, M.: Layered black phosphorus as a selective vapor sensor. B. Condens. Calculated formation energy from the elements normalized to per atom in the unit cell. Mater. Eswaraiah, V., Zeng, Q.S., Long, Y., Liu, Z.: Black phosphorus nanosheets: synthesis, characterization and applications. Group V elements in crystal structure isostructural to black phosphorus with unique puckered two-dimensional layers exhibit exciting physical and chemical phenomena. Black phosphorus (BP) is one of the most stable allotropes among the three allotropes of phosphorus at a high temperature under a high pressure possessing new two-dimensional layered structure, which was first prepared by Bridgman in 1914. 160.153.154.25. Interfaces. Lee, C.H., Lee, G.H., van Der Zande, A.M., Chen, W., Li, Y., Han, M., Cui, X., Arefe, G., Nuckolls, C., Heinz, T.F., Guo, J., Hone, J., Kim, P.: Atomically thin p-n junctions with van der Waals heterointerfaces. Physica (Amsterdam), Peng, X., Wei, Q., Copple, A.: Strain-engineered direct-indirect band gap transition and its mechanism in two-dimensional phosphorene. Nanoscale. Nanoscale. The structure of black phosphorus naturally makes channels to let lithium in. D: Mechanical properties of single-layer black phosphorus. Figure 6. For more detail, pelase see B: Condens. B, Zhu, L., Zhang, G., Li, B.: Coexistence of size-dependent and size-independent thermal conductivities in phosphorene. Li, L.K., Yu, Y.J., Ye, G.J., Ge, Q.Q., Ou, X.D., Wu, H., Feng, D.L., Chen, X.H., Zhang, Y.B. Ling, X., Wang, H., Huang, S., Xia, F., Dresselhaus, M.S. : J. Photon. Takao, Y., Morita, A.: Electronic structure of black phosphorus in tight binding approach. Small. Introduction Black phosphorus is the most stable form of phosphorus at normal condition and has a layer structure consisting of puckered layers parallel to the xy plane (see fig. It should be noted that ComputedEntries assimilated using the Takao, Y., Akira, M.: Electronic structure of black phosphorus: tight binding approach. A. Phys. Ed. Black Phosphorus: The Birth of a New Wonder Material. Calculated powder diffraction pattern; note that peak spacings may be affected due to inaccuracies in calculated cell volume, which is typically overestimated on average by 3% (+/- 6%). Again, using the example of an Fe2O3 run Zhang, R., Zhou, X.Y., Zhang, D., Lou, W.K., Zhai, F., Chang, K.: Electronic and magneto-optical properties of monolayer phosphorene quantum dots. Low, T., Rodin, A.S., Carvalho, A., Jiang, Y., Wang, H., Xia, F., Neto, A.H.C. Angew. The structure is two-dimensional and consists of two P sheets oriented in the (0, 1, 0) direction. Choi, S.J., Kim, B.K., Lee, T.H., Kim, Y.H., Li, Z., Pop, E., Kim, J.J., Song, J.H., Bae, M.H. Nano Lett. Zhang, X., Xie, H., Liu, Z., Tan, C., Luo, Z., Li, H., Lin, J., Sun, L., Chen, W., Xu, Z., Xie, L., Huang, W., Zhang, H.: Black phosphorus quantum dots. Chem. Nat. Phys. Novoselov, K.S., Geim, A.K., Morozov, S.V., Jiang, D., Zhang, Y., Dubonos, S.V., Grigorieva, I.V., Firsov, A.A.: Electric field effect in atomically thin carbon films. J. Appl. this would look like entry.parameters["hubbards"] = {"Fe": 5.3} Am. This is a preview of subscription content. Rahman, M.Z., Kwong, C.W., Davey, K., Qiao, S.Z. Khandelwal, A., Mani, K., Karigerasi, M.H., Lahiri, I.: Phosphorene-the two-dimensional black phosphorous: properties, synthesis and applications. … Solid State Mater. : Black phosphorus nanoelectromechanical resonators vibrating at very high frequencies. if you ran a Fe2O3 calculation with Materials Project parameters, Appl. Chem. Chem. Wei, Q., Peng, X.: Superior mechanical flexibility of phosphorene and few-layer black phosphorus Appl. Mater. Nat. Not logged in black phosphorus; nanoelectronic; optoelectronic; anisotropic; 2D material; At the beginning of 2014, a few research teams including the ones led by the authors reintroduced black phosphorus (black P) from the perspective of a layered thin film material (1 ⇓ ⇓ ⇓ ⇓ –6), in which previously unidentified properties and applications have arisen.Since then, black … Keyes, R.: The electrical properties of black phosphorus. Nat. Nanotechnol. Control Release. Adv. Small Meth. Correct gas energies to obtain the right formation energies. Mater. : A black phosphorus carbide infrared phototransistor. Adv. The catalytic representation of black phosphorus. 2. In general, band gaps computed with common exchange-correlation functionals such as the LDA and GGA are severely underestimated. J. Phys. : Enhanced thermoelectric performance of phosphorene by strain-induced band convergence. Chem. Black phosphorus and its exfoliated product, phosphorene, are rising stars in the 2D materials field. Cite as. In 2014, several groups isolated single-layer phosphorene, a monolayer of black phosphorus. Since, the development and recent success in growing two-dimensional material family, single- or few-layered, BP has recently a vital field of interest due to their various superior properties, such as a tunable and direct/narrow band gaps, high carrier mobility, large specific surface area, photothermal property, biocompatibility, biodegradability and many interesting in-layer anisotropies and attracted considerable attention on applications in energy conversion and storage, oxygen evolution, electronics, optoelectronics, photocatalytic hydrogenation, water splitting, and thermoelectric generators, etc. Black phosphorene has attracted much attention as a semiconducting two-dimensional material. : Phosphorene nanoribbons, phosphorus nanotubes, and van der waals multilayers. History. Chem. It has a layered structure and is a highly polymerizedform of phosphorus. Yang, Y., Gao, J., Zhang, Z., Xiao, S., Xie, H.H., Sun, Z.B., Wang, J.H., Zhou, C.H., Wang, Y.W., Guo, X.Y. Bridgman, P.W. Lan, S., Rodrigues, S., Kang, L., Cai, W.: Visualizing optical phase anisotropy in black phosphorus. Sun, Z., Martinez, A., Wang, F.: Optical modulators with two-dimensional layered materials. USA, Liu, H., Neal, A.T., Zhu, Z., Luo, Z., Xu, X., Tomanek, D., Ye, P.D. Entry.parameters must contain a "potcar_symbols" key that is a list of section of our Calculations Guide. 2D Mater. Biomaterials, Choi, J.R., Yong, K.W., Choi, J.Y., Nilghaz, A., Lin, Y., Xu, J., Lu, X.: Black phosphorus and its biomedical applications. Brown, A., Rundqvist, S.: Refinement of the crystal structure of black phosphorus. Li, L., Chen, L., Mukherjee, S., Gao, J., Sun, H., Liu, Z., Ma, X., Gupta, T., Singh, C.V., Ren, W., Cheng, H.M., Koratkar, N.: Phosphorene as a polysulfide immobilizer and catalyst in high-performance lithium–sulfur batteries. Phys. There are two shorter (2.22 Å) and one longer (2.26 Å) P–P bond lengths. interface using the pymatgen.matproj.rest package will automatically have Phys. Matter. Bai, L., Sun, L., Wang, Y., Liu, Z., Gao, Q., Xiang, H., Xie, H., Zhao, Y.: Solution-processed black phosphorus/PCBM hybrid heterojunctions for solar cells. the Total S1), because for each layer, BP and SnSe bear a nearly identical hinge-like structure, which may … ensures that calculations performed using different InputSets are not Sci. ACS Nano, Guo, H., Lu, N., Dai, J., Wu, X., Zeng, X.C. Acad. J. 1 High-pressure polymeric nitrogen allotrope with the black phosphorus structure Dominique Laniel1*, Bjoern Winkler2, Timofey Fedotenko1, Anna Pakhomova3, Stella Chariton4, Victor Milman5, Vitali Prakapenka4, Leonid Dubrovinsky6, Natalia Dubrovinskaia1,7. absorption site in the structure. Owing to its high charge-carrier mobility, tunable direct-bandgap and unique in-plane anisotropic structure, black phosphorus (BP), a rising star of post-graphene two-dimensional (2D) nanomaterials, has been intensively investigated since early 2014. Chem. Nano Lett. As a 2D material, in appearance, properties, and structure, black phosphorus is very muc… Nat. Small, Huang, Y., Liu, X., Liu, Y., Shao, Y., Zhang, S., Fang, C., Han, G., Zhang, J., Hao, Y.: Nanostructured multiple-layer black phosphorus photodetector based on localized surface plasmon resonance. Commun. Soc. Phys. Note that https://doi.org/10.1016/j.biomaterials.2016.03.022, https://doi.org/10.1080/10408430903505036, https://doi.org/10.1016/j.mseb.2017.03.011, https://doi.org/10.1016/j.trac.2017.05.002, https://doi.org/10.1016/j.micromeso.2016.01.031, https://doi.org/10.1088/2053-1583/2/4/045012/meta, https://doi.org/10.1103/physrevb.86.035105, https://doi.org/10.1103/PhysRevB.90.205421, https://doi.org/10.1103/physrevb.90.075434, https://doi.org/10.1103/PhysRevB.89.235319, https://doi.org/10.1016/j.bios.2016.03.059, https://doi.org/10.1016/j.apmt.2016.05.001, https://doi.org/10.1038/s41566-018-0239-8, https://doi.org/10.1021/acs.jpclett.5b01686, https://doi.org/10.1021/acs.nanolett.5b04957, https://doi.org/10.1088/2053-1583/2/4/044014/pdf, https://doi.org/10.1103/PhysRevB.77.205429, https://doi.org/10.1016/j.biomaterials.2018.02.040, https://doi.org/10.1016/j.jconrel.2019.01.027, https://doi.org/10.1016/0378-4363(81)90222-9, https://doi.org/10.1103/PhysRevB.90.085402, https://doi.org/10.1088/0022-3727/47/38/385304/meta, https://doi.org/10.1103/PhysRevLett.112.176801, https://doi.org/10.1107/S0365110X65004140, https://doi.org/10.1088/2053-1583/1/2/025001, https://doi.org/10.1103/physrevb.90.085433, https://doi.org/10.1103/physrevb.90.214302, https://doi.org/10.1103/PhysRevB.89.035438, https://doi.org/10.1021/acsphotonics.6b00320, https://doi.org/10.1016/0378-4363(81)90223-0, https://doi.org/10.1007/978-3-030-29555-4_7. We present an overview on the electronic band structure of surface-doped black phosphorus. Chem. Here, we report the synthesis of the black phosphorus–structured nitrogen at 146 GPa and 2200 K. Metastable black … Brown and S. Rundqvist. Through high resolution photon energy dependence measurements, the band dispersions along out-of-plane and in-plane directions are experimentally … : Epitaxial growth of a monolayer WSe, Huo, N.J., Kang, J., Wei, Z.M., Li, S.S., Li, J.B., Wei, S.H. Soc. Especially, there emerge contributions on electrochemical energy storage devices as supercapacitors and in batteries like lithium/sodium ion batteries. : Ultrasmall black phosphorus quantum dots: synthesis and use as photothermal agents. Chem. Phys. Chem. 7: Preparation and Properties of Alpha Black Phosphoru… Fu, Y., Wei, Q., Zhang, G., Sun, S.: Advanced phosphorus-based materials for lithium/sodium-ion batteries: recent developments and future perspectives. C, Cai, Y., Lan, J., Zhang, G., Zhang, Y.W. When individual layers of black phosphorus are separated from the bulk crystal through mechanical exfoliation or sonication, the resulting 2D layers of phosphorene have atoms arranged in a puckered honeycomb structure. ACS Photon. Qiao, J., Kong, X., Hu, Z.X., Yang, F., Ji, W.: High-mobility transport anisotropy and linear dichroism in few-layer black phosphorus. The oxidation of BP caused by air exposure gives several optical signatures, including the broadening of resonance peaks and … We additionally find that several known insulators are predicted to be metallic. Nano Lett. : High-performance n-type black phosphorus transistors with type control via thickness and contact-metal engineering. structures displayed (dissimilarity threshold 0.75). Black Phosphorus properties: α-black and β-black are two forms of black phosphorus. 4 A shows the calculated band structure for monolayer, bilayer, and trilayer black phosphorus by ab initio calculations with the GW approximation (Rudenko and Katsnelson, 2014).The band … J. Phys. Black phosphorus, which is a relatively rare allotrope of phosphorus, was first discovered by Bridgman in 1914. Biosens. Chem. John Timmer - Oct 11, 2020 1:30 pm UTC Enlarge / Layers of phosphorene sheets form black … Black Phosphorus. : Strongly anisotropic in-plane thermal transport in single-layer black phosphorene. B: Condens. J. Entry.parameters must contain a "hubbards" key which is a dict : Semiconducting black phosphorus: synthesis, transport properties and electronic applications. When white form is … Some internal testing by the Materials Project supports these statements; typically, we find that band gaps are underestimated by ~40%. pymatgen.apps.borg package and obtained via the MaterialsProject REST Chem. Am. Ed. Proc. Sci. : Black phosphorus field-effect transistors. Checks that POTCARs are valid within a pre-defined input set. Acta Crystallogr. In article number 1909372, Lili Wang, Wei Han, and co‐workers develop a high‐performance lithium ion battery based on a black phosphorus@CNT hybrid with a 3D chemical cross‐linking structure.With its strong trapping, good affinity, structural stability, and high adsorption for polyphosphorus, the developed … Mater. The calculated bulk crystalline density, typically underestimated due calculated cell volumes overestimated on average by 3% (+/- 6%). : Thermoelectric terahertz photodetectors based on selenium-doped black phosphorus flakes. Rev. Jia, Z.Y., Xiang, J.Y., Mu, C.P., Wen, F.S., Yang, R.L., Hao, C.X., Liu, Z.Y. of all non-zero Hubbard U values used in the calculation. B. Tran, V., Soklaski, R., Liang, Y., Yang, L.: Layer-controlled band gap and anisotropic excitons in few-layer black phosphorus. : Novel and enhanced optoelectronic performances of multilayer MoS, Cheng, R., Li, D., Zhou, H., Wang, C., Yin, A., Jiang, S., Liu, Y., Chen, Y., Huang, Y., Duan, X.: Electroluminescence and photocurrent generation from atomically sharp WSe. Follow IUCr Journals: E-alerts: Twitter: Facebook: RSS: Search IUCr Journals: doi: Advanced search: Author Nanoscale. It was first synthesized by heating white phosphorus under high pressures (12,000 atmospheres) in 1914. never been found in the black phosphorus structure. : Anisotropic thermal conductivity of exfoliated black phosphorus. Ball-and-stick model of a sheet of phosphorus atoms in black phosphorus. Late, D.J. Black phosphorus is the thermodynamically stable form of phosphorus at room temperature and pressure, with a heat of formationof -39.3 kJ/mol (relative to white phosphorus which is defined as the standard state). Rev. all POTCARs used in the run. This allotrope has been shown to exhibit high carrier mobility. The layers are stacked together via van der Waals interactions and can be exfoliated into thin 2D layers down to single layer phosphorus (phosphorene). Commun. This class implements the GGA/GGA+U mixing scheme, which allows mixing of Up to 5 similar elemental, binary, ternary, quaternary, etc. Materials scientists have discovered how to make black phosphorus nanosheets in large amounts, heralding a new era of nanoelectronic devices. Soc. Phys. Rep. Jiang, J.W., Park, H.S. these fields populated. Typically the disagreement is reported to be ~50% in the literature. Crichton, W.A., Mezouar, M., Monaco, G., Falconi, S.: Phosphorus: new in situ powder data from large-volume apparatus. Miao, J., Song, B., Xu, Z., Cai, L., Zhang, S., Dong, L., Wang, C.: Single pixel black phosphorus photodetector for near-infrared imaging. J. Phys. Phys. Black phosphorus is the most stable allotrope of phosphorus, which also occurs in the form of white, red and violet phosphorus. Rev. A, Zhu, M., Cai, X., Fujitsuka, M., Zhang, J., Majima, T.: Au/La, He, J., He, D., Wang, Y., Cui, Q., Bellus, M.Z., Chiu, H.Y., Zhao, H.: Exceptional and anisotropic transport properties of photocarriers in black phosphorus. Rev. Mater. Martinez, C.C.M., Sofer, Z., Sedmidubsky, D., Luxa, J., Kherzia, B., Pumera, M.: Metallic impurities in black phosphorus nanoflakes prepared by different synthetic routes. Phys. Mater. Soc. No satisfactory crystal structure determination has been made of any of the forms of phosphorus. B. Qin, G., Yan, Q.B., Qin, Z., Yue, S.Y., Cui, H.J., Zheng, Q.R., Su, G.: Hinge-like structure induced unusual properties of black phosphorus and new strategies to improve the thermoelectric performance. : Negative poisson’s ratio in single-layer black phosphorus. Woomer, A.H., Farnsworth, T.W., Hu, J., Wells, R.A., Donley, C.L., Warren, S.C.: Phosphorene: synthesis, scale-up, and quantitative optical spectroscopy. Tran, V., Fei, R., Yang, L.: Quasiparticle energies, excitons, and optical spectra of few-layer black phosphorus. Xia, F., Wang, H., Jia, Y.: Rediscovering black phosphorus as an anisotropic layered material for optoelectronics and electronics. But this required a supply of white phosphorus, which is comparatively hard to find. pp 139-156 | VIII. Adv. : The renaissance of black phosphorus. We show that it is also vulnerable to air exposure. Sci. Opt. Chem. Adv. Mater. Small. Sun, C., Wen, L., Zeng, J., Wang, Y., Sun, Q., Deng, L., Zhao, C., Li, Z.: One-pot solvent less preparation of PEGylated black phosphorus nanoparticles for photoacoustic imaging and photothermal therapy of cancer. Fig. 'PAW_PBE O 08Apr2002']. A sample which had … BP following EMIM:TFSI doping achieves a high hole density of up to 1013 cm–2, which represents a degenerate doping level. J. Phys. Fig. Rev. Sun, Z., Xie, H., Tang, S., Yu, X.F., Guo, Z., Shao, J., Zhang, H., Huang, H., Wang, H., Chu, P.K. this depends on calculations being run within the same input set. Lett. Phys. ACS Appl. Typically accurate to the second digit. Z.: About the structure and properties of semi-metals. Jan Plutnar, Jiří Šturala, Vlastimil Mazánek, Zdeněk Sofer, Martin Pumera, Fluorination of Black Phosphorus—Will Black Phosphorus Burn Down in the Elemental Fluorine?, Advanced Functional Materials, … Zhao, W., Xue, Z., Wang, J., Jiang, J., Zhao, X., Mu, T.: Large-Scale, Highly efficient, and green liquid-exfoliation of black phosphorus in ionic liquids. It does not oxidize in the air. Appl. Adv. Sun, J., Zheng, G., Lee, H.W., Liu, N., Wang, H., Yao, H.: Formation of stable phosphorus-carbon bond for enhanced performance in black phosphorus nanoparticle-graphite composite battery anodes. Stability is tested against all potential chemical combinations that result in the material's composition. P is bonded in a trigonal non-coplanar geometry to three equivalent P atoms. Note that Liu, X., Ryder, C.R., Wells, S.A., Hersam, M.C. Mao, N., Tang, J., Xie, L., Wu, J., Han, B., Lin, J., Deng, S., Ji, W., Xu, H., Liu, K., Tong, L., Zhang, J.: Optical anisotropy of black phosphorus in the visible regime. Lei, W., Liu, G., Zhang, J., Liu, M.: Black phosphorus nanostructures: recent advances in hybridization, doping and functionalization. Allg. Ed. Energy Environ. Rev. Viti, L., Hu, J., Coquillat, D., Knap, W., Tredicucci, A., Politano, A., Vitiello, M.S. 6: The Layered Structure of Black Phosphorus 1. Appalakondaiah, S., Vaitheeswaran, G., Lebegue, S., Christensen, N.E., Svane, A.: Effect of van der Waals interactions on the structural and elastic properties of black phosphorus. Perello, D.J., Chae, S.H., Song, S., Lee, Y.H. Calculated total magnetic moment for the unit cell within the magnetic ordering provided (see below). : Black phosphorus terahertz photodetectors. The applications of phosphorene and its functionalized derivatives in devices are also reported. Ceballos, F., Bellus, M.Z., Chiu, H.Y., Zhao, H.: Ultrafast charge separation and indirect exciton formation in a MoS, Rivera, P., Schaibley, J.R., Jones, A.M., Ross, J.S., Wu, S., Aivazian, G., Klement, P., Seyler, K., Clark, G., Ghimire, N.J., Yan, J., Mandrus, D.G., Yao, W., Xu, X.: Observation of long-lived interlayer excitons in monolayer MoSe. B. Chen, Y., Ren, R., Pu, H., Chang, J., Mao, S., Chen, J.: Field-effect transistor biosensors with two-dimensional black phosphorus nanosheets. Soc. Tan, W.C., Huang, L., Ng, R.J., Wang, L., Hasan, D.M.N., Duffin, T.J., Kumar, K.S., Nijhuis, C.A., Lee, C., Ang, K.W. Rodin, A., Carvalho, A., Neto, A.C.: Strain-induced gap modification in black phosphorus. Phys. Microporous Mesoporous Mater. : Isolation and characterization of few-layer black phosphorus. Bioelectron. Adv. Rev. J. Phys. 1). Appl. Chem. entries. Angew. Powder Diffr. Mater. Bullock, J., Amani, M., Cho, J., Chen, Y.Z., Ahn, G.H., Adinolfi, V., Shrestha, V.R., Gao, Y., Crozier, K.B., Chueh, Y.L., Javey, A.: Polarization-resolved black phosphorus/molybdenum disulfide mid-wave infrared photodiodes with high detectivity at room temperature. Correct anion energies to obtain the right formation energies. Nanotechnol. Dhanabalan, S.C., Ponraj, J.S., Guo, Z., Li, S., Bao, Q., Zhang, H.: Emerging trends in phosphorene fabrication towards next generation devices. J. Phys. Xu, R., Yang, J., Myint, Y.W., Pei, J., Yan, H., Wang, F., Lu, Y.: Exciton brightening in monolayer phosphorene via dimensionality modification. It is this structure which gives the material its fascinating properties. C. Sun, J., Lee, H.W., Pasta, M., Yuan, H., Zheng, G., Sun, Y., Li, Y., Cui, Y.: A phosphorene-graphene hybrid material as a high-capacity anode for sodium-ion batteries. We report the versatile doping control of black phosphorus (BP) using an ionic liquid (EMIM:TFSI) as a surface charge acceptor for a wide range of electronic and optoelectronic device applications. The electronic structure of few-layer (FL) black phosphorus (BP) sensitively depends on the sample thickness, strain, and doping. Yu, J.H., Lee, H.R., Hong, S.S., Kong, D.S., Lee, H.W., Wang, H.T., Xiong, F., Wang, S., Cui, Y.: Vertical heterostructure of two-dimensional MoS, Li, M.Y., Shi, Y.M., Cheng, C.C., Lu, L.S., Lin, Y.C., Tang, H.L., Tsai, M.L., Chu, C.W., Wei, K.H., He, J.H., Chang, W.H., Suenaga, K., Li, L.J. Jpn. Choi, W., Lahiri, I., Seelaboyina, R., Kang, Y.S. The role of inorganic chemistry is presented, the black phosphorus surface being a potential anchoring point for metal fragments. P is black P structured and crystallizes in the orthorhombic Cmce space group. Sci. Rev. When red phosphorus is heated in a sealed tube at 803K, an α-black form is formed. : Thermoelectric terahertz photodetectors based on selenium-doped black phosphorus flakes. Refinement of the crystal structure of black phosphorus. Lett. Energy Mater. 2D Mater. To explore its full potential and push the limits, researc : 2D phosphorene as a water splitting photocatalyst: fundamentals to applications. Chen, Y., Jiang, G., Chen, S., Guo, Z., Yu, X., Zhao, C., Zhang, H., Bao, Q., Wen, S., Tang, D., Fan, D.: Mechanically exfoliated black phosphorus as a new saturable absorber for both Q-switching and mode-locking laser operation. : Synthesis of graphene and its applications: A review. This is the first page of the article you requested. View JMOL 3-D Structure : Phosphorus : Cartz L, Srinivasa S R, Riedner R J, Jorgensen J D, Worlton T G : Journal of Chemical Physics 71 (1979) 1718-1721: Effect of pressure on bonding in black phosphorus: Locality: synthetic: Note: pressures calculated from the measured unit cell volume _database_code_amcsd 0013008: … Express. In its bulk form, black phosphorus is a direct-gap semiconductor with a 0.33 eV bandgap and mobilities of up to 20 000 cm 2 Vs −1 at room temperature [16–18].Unlike other allotropes, black phosphorus is characterized by a layered structure… this depends on calculations being run within the same input set. However, no confirmed violet crystals or reliable lattice structure of violet ph … Angle-resolved photoemission spectroscopy data show that the in situ deposition of potassium atoms on the surface of single-crystalline black phosphorus modulates the band gap in the wide range of 0.0–0.6 eV. 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2020 structure of black phosphorus